Innovating Greener Catalytic Processes for Carbon Dioxide Utilization, Storage and Hydrogen Production
Research
Our research is broadly focused on heterogeneous catalyst and process development for carbon dioxide utilization and hydrogen production reactions of contemporary interest, including CO2 hydrogenation, methane dry reforming, biomass gasification and methane pyrolysis. Major thrusts of our research program include (1) understanding and developing novel material architectures (e.g., core-shell catalysts and layered phyllosilicate precursors) for enhanced catalytic performance, and (2) designing and engineering catalytic membrane reactors that overcome conventional thermodynamic limitations by integrating reaction and product separation steps. We have also recently begun to explore photothermal, electrochemical and plasma-based approaches to lower the often-high operating temperature requirements typical of heterogeneously catalyzed reactions. Please read on for short summaries of some of our recent and ongoing projects.
Methane Pyrolysis for Hydrogen and Carbon Nanotube Production via Catalytic Membrane Reactor
Catalytic Membrane Gasification Technology for Syngas and Hydrogen Production from Waste
Chemical Looping for Hydrocarbon Reforming
Chemical looping reforming of biomass/hydrocarbons is a promising avenue for hydrogen generation. Both the design of reactor configurations and the screening of oxygen carriers represent major challenges in chemical looping technologies. In recent work, we have (1) developed sinter-resistant redox metal oxides as oxygen carriers, (2) achieved isothermal cyclic CO2 capture and dry reforming using a novel bifunctional Ni/CeO2-CaO material, and (3) mitigated the coking challenge of conventional dry reforming via a novel methane-nitric oxide chemical looping process.
Advanced Catalytic Membrane Reactor to Co-Produce Propylene and Methane from Propane and CO2
Design of Stable and Coke-Resistant Ni-Based Dry Reforming Catalysts
Past and Present Collaborators:
​
-
Prof. Chi-Hwa Wang (National Univ. of Singapore)
-
Prof. Ghim Wei Ho (National Univ. of Singapore)
-
Prof. Lei Wang (National Univ. of Singapore)
-
Dr. Armando Borgna (A*STAR, Singapore)
-
Dr. Jie Chang (A*STAR, Singapore)
-
Prof. Bruce C. Gates (UC-Davis, USA)
-
Prof. Jerry Y. S. Lin (Arizona State Univ., USA)
-
Prof. Michael P. Harold (Univ. Houston, USA)
-
Prof. James J. Spivey (Louisiana State Univ., USA)
-
Prof. Keiichi Tomishige (Tohoku Univ., Japan)
-
Prof. Shaomin Liu (Curtin Univ., Australia)
-
Prof. Yuhan Sun (Chinese Academy of Sciences)
-
Prof. Jinlong Gong (Tianjin Univ., China)
-
Prof. Xinbin Ma (Tianjin Univ., China)
-
Prof. Javier Perez-Ramirez (ETH Zurich, Switzerland)
-
Prof. Ange Nzihou (IMT Mines Albi, France)
-
Prof. Yongdan Li (Aalto Univ., Finland)
-
Prof. Michele Aresta (Univ. Bari, Italy)